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Sodium ferrocyanide is the sodium salt of the coordination compound of formula [Fe(CN) 6] 4−. In its hydrous form, Na 4 Fe(CN) 6 · H 2 O (sodium ferrocyanide decahydrate), it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ...
Ferrocyanide is the name of the anion [Fe 6] 4−. Salts of this coordination complex give yellow solutions. It is usually available as the salt potassium ferrocyanide, which has the formula K 4 Fe(CN) 6. [Fe(CN) 6] 4− is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment.
2 K 4 [Fe(CN) 6] + Cl 2 → 2 K 3 [Fe(CN) 6] + 2 KCl. This reaction can be used to remove potassium hexacyanidoferrate(II) from a solution. [citation needed] A famous reaction involves treatment with ferric salts, most commonly Iron(III) chloride, to give Prussian blue. In the reaction with Iron(III) chloride, producing Potassium chloride as a ...
A well known couple is [Fe(CN) 6] 3−/4−. Mn(IV), Mn(III), and Mn(II) are known for hexacyanomanganate. Mn(IV), Mn(III), and Mn(II) are known for hexacyanomanganate. Few unidentate ligands allow similar redox transformations wherein both members of the redox couple are observable in solution.
Fe(CN) 4− 6 + 6 H + + 2 e −: ⇌ Fe(s) + 6HCN(aq) -1.16 2 [12] C: C(s) + 3 H 2 O (l) + 2 e −: ⇌: CH 3 OH (l) + 2 OH −-1.148: 2 [6]: 788 Cr: Cr(CN) 3− 6 + e −: ⇌: Cr(CN) 4− 6-1.143: 1 [6]: 793 Te Te(s) + 2 e −: ⇌ Te 2−-1.143 2 [13] V V 2+ + 2 e −: ⇌ V(s) -1.13 2 [13] Nb Nb 3+ + 3 e −: ⇌ Nb(s) -1.099 3 [8] Sn Sn(s ...
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Cyanogen azide is a chemical compound with the chemical formula C N 4, or more precisely − N=N + =N−C≡N. It is an azide compound of carbon and nitrogen. It is an oily, colourless liquid at room temperature. [2] It is a highly explosive chemical that is soluble in most organic solvents, and normally handled in dilute solution in this form.