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An electron donating group (EDG) or electron releasing group (ERG, Z in structural formulas) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance (mesomerism) or inductive effects (or induction)—called +M or +I effects, respectively—thus making the π system more nucleophilic.
Delocalizing the radical ion stabilizes the transition state structure. As a result, the energy of activation decreases, enhancing the rate of the overall reaction. According to the captodative effect, the rate of a reaction is the greatest when both the EDG and EWG are able to delocalize the radical ion in the transition state structure. [7]
An electron-withdrawing group (EWG) is a group or atom that has the ability to draw electron density toward itself and away from other adjacent atoms. [1] This electron density transfer is often achieved by resonance or inductive effects.
The EWG withdraws electron density by resonance and effectively stabilizes the negative charge that is generated. The corresponding plot will show a positive rho value. In the case of a nucleophilic acyl substitution the effect of the substituent, X, of the non-leaving group can in fact accelerate the rate of the nucleophilic addition reaction ...
Download QR code; Print/export Download as PDF; Printable version; ... move to sidebar hide. EDG may refer to: Science and medicine Electron donating group, a ...
You may be familiar with the Environmental Working Group (EWG) because they release a list of the most pesticide-filled produce every year called The Dirty Dozen. They also establish the produce ...
EWG may refer to: Eastern Washington Gateway Railroad, an American railroad; East-West Gateway Council of Governments, a planning organization in Greater St. Louis, United States; Election Working Group, a Bangladeshi civic organization; Electron withdrawing group; Energy Watch Group, an international energy think tank; English Whisky Guild, an ...
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