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  2. Charge-transfer band - Wikipedia

    en.wikipedia.org/wiki/Charge-transfer_band

    Charge-transfer bands of transition metal complexes result from shift of charge density between molecular orbitals (MO) that are predominantly metal in character and those that are predominantly ligand in character. If the transfer occurs from the MO with ligand-like character to the metal-like one, the transition is called a ligand-to-metal ...

  3. Transition metal complexes of 2,2'-bipyridine - Wikipedia

    en.wikipedia.org/wiki/Transition_metal_complexes...

    The electronic transitions are attributed to metal-to-ligand charge transfer (MLCT). In the "tris(bipy) complexes" three bipyridine molecules coordinate to a metal ion, written as [M(bipy) 3 ] n + (M = metal ion; Cr, Fe, Co, Ru, Rh and so on).

  4. Charge-transfer complex - Wikipedia

    en.wikipedia.org/wiki/Charge-transfer_complex

    In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...

  5. Intersystem crossing - Wikipedia

    en.wikipedia.org/wiki/Intersystem_crossing

    Once a metal complex undergoes metal-to-ligand charge transfer, the system can undergo intersystem crossing, which, in conjunction with the tunability of MLCT excitation energies, produces a long-lived intermediate whose energy can be adjusted by altering the ligands used in the complex.

  6. Transition metal - Wikipedia

    en.wikipedia.org/wiki/Transition_metal

    A metal-to-ligand charge transfer (MLCT) transition will be most likely when the metal is in a low oxidation state and the ligand is easily reduced. In general charge transfer transitions result in more intense colours than d–d transitions. d–d transitions. An electron jumps from one d orbital to another. In complexes of the transition ...

  7. Transition metal oxo complex - Wikipedia

    en.wikipedia.org/wiki/Transition_metal_oxo_complex

    A transition metal oxo complex is a coordination complex containing an oxo ligand. Formally O 2–, an oxo ligand can be bound to one or more metal centers, i.e. it can exist as a terminal or (most commonly) as bridging ligands. Oxo ligands stabilize high oxidation states of a metal. [1]

  8. Photoredox catalysis - Wikipedia

    en.wikipedia.org/wiki/Photoredox_catalysis

    For many metal-based sensitizers, excitation is realized as a metal-to-ligand charge transfer, whereby an electron moves from the metal (e.g., a d orbital) to an orbital localized on the ligands (e.g. the π* orbital of an aromatic ligand).

  9. Metal L-edge - Wikipedia

    en.wikipedia.org/wiki/Metal_L-edge

    This is commonly known as ligand-to-metal charge transfer or LMCT. In some cases, low-lying unoccupied ligand orbitals (π*) can receive back-donation (or backbonding) from the occupied metal orbitals. This has the opposite effect on the system, resulting in metal-to-ligand charge transfer, MLCT, and commonly appears as an additional L-edge ...