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Arrhenius plot. In chemical kinetics, an Arrhenius plot displays the logarithm of a reaction rate constant, ( , ordinate axis) plotted against reciprocal of the temperature ( , abscissa). [1] Arrhenius plots are often used to analyze the effect of temperature on the rates of chemical reactions. For a single rate-limited thermally activated ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
C 6 H 6 (l) 124.5. 31.00. The standard Gibbs free energy of formation of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of that substance from its component elements, in their standard states (the most stable form of the element at 25 °C and 100 kPa). Its symbol is Δ fG ˚.
Four-bar linkage. In the study of mechanisms, a four-bar linkage, also called a four-bar, is the simplest closed- chain movable linkage. It consists of four bodies, called bars or links, connected in a loop by four joints. Generally, the joints are configured so the links move in parallel planes, and the assembly is called a planar four-bar ...
Lineweaver–Burk plot. An example of a Lineweaver–Burk plot of 1/ v against 1/ a. In biochemistry, the Lineweaver–Burk plot (or double reciprocal plot) is a graphical representation of the Michaelis–Menten equation of enzyme kinetics, described by Hans Lineweaver and Dean Burk in 1934. [1]
Shortest path problem. Shortest path (A, C, E, D, F) between vertices A and F in the weighted directed graph. In graph theory, the shortest path problem is the problem of finding a path between two vertices (or nodes) in a graph such that the sum of the weights of its constituent edges is minimized. [1]
An graph (or a component) with an odd number of vertices cannot have a perfect matching, since there will always be a vertex left alone. The goal is to characterize all graphs that do not have a perfect matching. Start with the most obvious case of a graph without a perfect matching: a graph with an odd number of vertices.