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Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions result in a perceptible or notable change; these successful changes are called successful collisions.
According to collision theory, the frequency factor, A, depends on how often molecules collide when all concentrations are 1 mol/L and on whether the molecules are properly oriented when they collide. Values of A for some reactions can be found at Collision theory.
In 1918 he propounded his theory of chemical reaction which came to be called the "Collision Theory". A similar theory was also propounded by Max Trautz in Germany in 1916, unbeknown to Lewis because of the first World War. [1] In 1926 he was elected a Fellow of the Royal Society.
Also called the probability factor, the steric factor is defined as the ratio between the experimental value of the rate constant and the one predicted by collision theory. It can also be defined as the ratio between the pre-exponential factor and the collision frequency , and it is most often less than unity.
One of the simplest models of reaction rate is the collision theory. More realistic models are tailored to a specific problem and include the transition state theory, the calculation of the potential energy surface, the Marcus theory and the Rice–Ramsperger–Kassel–Marcus (RRKM) theory. [20]
Collision frequency describes the rate of collisions between two atomic or molecular species in a given volume, per unit time. In an ideal gas , assuming that the species behave like hard spheres, the collision frequency between entities of species A and species B is: [ 1 ]
Elastic collision If all of the total kinetic energy is conserved (i.e. no energy is released as sound, heat, etc.), the collision is said to be perfectly elastic. Such a system is an idealization and cannot occur in reality, due to the second law of thermodynamics .
Introduction to the theory and applications of dispersion relations. Hermann. (In Relations de dispersion et particules élémentaires: École d'été de physique théorique, Les Houches, 1960) Marvin L. Goldberger & Kenneth M. Watson (2004). Collision Theory. Dover. ISBN 0-486-43507-5. (corrected version of book originally published in 1964)