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To change this template's initial visibility, the |state= parameter may be used: {{Stereochemistry | state = collapsed}} will show the template collapsed, i.e. hidden apart from its title bar. {{Stereochemistry | state = expanded}} will show the template expanded, i.e. fully visible. Mainly based on articles Descriptor (Chemistry) and Absolute ...
Stereochemistry, a subdiscipline of chemistry, studies the spatial arrangement of atoms that form the structure of molecules and their manipulation. [1] The study of stereochemistry focuses on the relationships between stereoisomers, which are defined as having the same molecular formula and sequence of bonded atoms (constitution) but differing in the geometric positioning of the atoms in space.
English: Skeletal formula of sertraline — an SSRI with its stereochemistry configuration highlighted. Created with ChemDoodle 7.0.2 and Adobe Illustrator CC 2015 . Date
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The parent cyclobutadiene (R = H) readily dimerizes but the R = tert-butyl derivative is robust. [1]Steric effects arise from the spatial arrangement of atoms. When atoms come close together there is generally a rise in the energy of the molecule.
An example of modest stereoselectivity is the dehydrohalogenation of 2-iodobutane which yields 60% trans-2-butene and 20% cis-2-butene. [5] Since alkene geometric isomers are also classified as diastereomers, this reaction would also be called diastereoselective.
In chemistry, dynamic stereochemistry studies the effect of stereochemistry on the reaction rate of a chemical reaction. Stereochemistry is involved in: stereospecific reactions; stereoselective or asymmetric reactions; racemisation processes
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