Search results
Results from the WOW.Com Content Network
Example of saponification reaction of a triglyceride molecule (left) with potassium hydroxide (KOH) yielding glycerol (purple) and salts of fatty acids ().. Saponification value or saponification number (SV or SN) represents the number of milligrams of potassium hydroxide (KOH) or sodium hydroxide (NaOH) required to saponify one gram of fat under the conditions specified.
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate ...
An approximate chemical formula for beeswax is C 15 H 31 COOC 30 H 61. [10] Its main constituents are palmitate , palmitoleate , and oleate esters of long-chain (30–32 carbons) aliphatic alcohols , with the ratio of triacontanyl palmitate CH 3 (CH 2 ) 29 O-CO-(CH 2 ) 14 CH 3 to cerotic acid CH 3 (CH 2 ) 24 COOH, the two principal constituents ...
The Reichert value is an indicator of how much volatile fatty acid can be extracted from a particular fat or oil through saponification. It is equal to the number of millilitres of 0.1 normal hydroxide solution necessary for the neutralization of the water-soluble volatile fatty acids distilled and filtered from 5 grams of a given saponified fat.
Cold water should be used since hot-water solutions can corrode steel. [67] Sodium bicarbonate attacks the thin protective oxide layer that forms on aluminium, making it unsuitable for cleaning this metal. [68] A solution in warm water will remove the tarnish from silver when the silver is in contact with a piece of aluminium foil.
Sodium methoxide is prepared by treating methanol with sodium: 2 Na + 2 CH 3 OH → 2 CH 3 ONa + H 2. The reaction is so exothermic that ignition is possible. The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol.
Such a triglyceride has a high iodine value (approx. 119). Below, the reaction product after the addition of four equivalents of iodine or bromine to the four C=C double bonds of the unsaturated fatty acid residues. The determination of iodine value is a particular example of iodometry. A solution of iodine I 2 is yellow/brown in color.
In this reaction, the triglyceride fats are first hydrolyzed into free fatty acids, and then these combine with the alkali to form crude soap: a combination of various soap salts, excess fat or alkali, water, and liberated glycerol (glycerin). [9] Saltwater soaps are potassium salts rather than sodium salts. Both sodium and potassium are alkali ...