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  2. Trimethyl orthoformate - Wikipedia

    en.wikipedia.org/wiki/Trimethyl_orthoformate

    Trimethyl orthoformate is a useful building block for creating methoxymethylene groups and heterocyclic ring systems. It introduces a formyl group to a nucleophilic substrate, e.g. RNH 2 to form R-NH-CHO, which can undergo further reactions.

  3. Methoxy group - Wikipedia

    en.wikipedia.org/wiki/Methoxy_group

    The structure of a typical methoxy group. In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen.This alkoxy group has the formula R−O−CH 3.

  4. Tetramethyl orthosilicate - Wikipedia

    en.wikipedia.org/wiki/Tetramethyl_orthosilicate

    Tetramethyl orthosilicate (TMOS) is the chemical compound with the formula Si(OCH 3) 4.This molecule consists of four methoxy groups bonded to a silicon atom. The basic properties are similar to the more popular tetraethyl orthosilicate, which is usually preferred because the product of hydrolysis, ethanol, is less toxic than methanol.

  5. Trimethoxysilane - Wikipedia

    en.wikipedia.org/wiki/Trimethoxysilane

    Trimethoxysilane is an important substance for producing silane coupling agents. It contains both hydrolyzable siloxane bonds as well as an active silicon-hydrogen bond. . Thereby it can be utilized in a series of reactions, such as copolymerization, polycondensation, and disproportionation reacti

  6. Wittig reagents - Wikipedia

    en.wikipedia.org/wiki/Wittig_reagents

    The alkylphosphonium salt is deprotonated with a strong base such as n-butyllithium: [Ph 3 P + CH 2 R]X − + C 4 H 9 Li → Ph 3 P=CHR + LiX + C 4 H 10. Besides n-butyllithium (n BuLi), other strong bases like sodium and potassium t-butoxide (t BuONa, t BuOK), lithium, sodium and potassium hexamethyldisilazide (LiHMDS, NaHMDS, KHDMS, where HDMS = N(SiMe 3) 2), or sodium hydride (NaH) are also ...

  7. Trimethyl borate - Wikipedia

    en.wikipedia.org/wiki/Trimethyl_borate

    Trimethyl borate is the main precursor to sodium borohydride by its reaction with sodium hydride in the Brown-Schlesinger process: . 4 NaH + B(OCH 3) 3 → NaBH 4 + 3 NaOCH 3. It is a gaseous anti-oxidant in brazing and solder flux.

  8. Trimethyl phosphite - Wikipedia

    en.wikipedia.org/wiki/Trimethyl_phosphite

    Trimethyl phosphite is an organophosphorus compound with the formula P(OCH 3) 3, often abbreviated P(OMe) 3.It is a colorless liquid with a highly pungent odor. It is the simplest phosphite ester and finds used as a ligand in organometallic chemistry and as a reagent in organic synthesis.

  9. Ortho effect - Wikipedia

    en.wikipedia.org/wiki/Ortho_effect

    Nitration of m-Nitrotoluene. The ortho effect also occurs when a meta-directing group is positioned in a meta arrangement relative to an ortho–para-directing group, a new substituent introduced into the molecule tends to preferentially occupy the ortho position relative to the meta-directing group rather than the para position.