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Benzyl bromide is a strong lachrymator and is also intensely irritating to skin and mucous membranes. Because of these properties, it has been used in chemical warfare , both in combat and in training due to its irritating yet non-lethal nature.
Benzyl bromide is an isomer, which has a bromine substituted for one of the hydrogens of toluene's methyl group, and it is sometimes named α-bromotoluene.
Benzyl is not to be confused with phenyl with the formula C 6 H 5. The term benzylic is used to describe the position of the first carbon bonded to a benzene or other aromatic ring. For example, (C 6 H 5)(CH 3) 2 C + is referred to as a "benzylic" carbocation. The benzyl free radical has the formula C 6 H 5 CH 2 •.
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It is a colorless liquid that is used as a fragrance and flavorant. It occurs naturally but is produced by reduction of the aldehyde or carboxylic acid. [ 2 ] It reacts with hydrogen bromide to give 4-methoxylbenzyl bromide .
Anet and Leblanc also in 1957 prepared a benzyl chromium solution from benzyl bromide and chromium(II) perchlorate. [8] This reaction involves one-electron oxidative addition of the carbon-bromine bond , a process which was shown by Kochi [ 9 ] [ 10 ] to be a case of double single electron transfer , first to give the benzyl free radical and ...
Benzyl alcohol is used effectively for treating lice infestations as the active ingredient in lotion shampoo with 5% benzyl alcohol. [13] Benzyl alcohol is an ingredient used in the manufacture of soaps, topical creams, skin lotions, shampoos, and facial cleansers and is popular due to its anti-bacterial and anti-fungal properties.
Benzyl iodide is an organic compound with the chemical formula C 7 H 7 I. [1] [2] The compound consists of a benzene ring with an attached iodidemethyl group. The substance is an alkyl halide and is a constitutional isomer of the iodotoluenes.