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The PUREX process was invented by Herbert H. Anderson and Larned B. Asprey at the Metallurgical Laboratory at the University of Chicago, as part of the Manhattan Project under Glenn T. Seaborg; their patent "Solvent Extraction Process for Plutonium" filed in 1947, [14] mentions tributyl phosphate as the major reactant which accomplishes the ...
The first reprocessing approach is based on the PUREX (Plutonium Uranium Reduction EXtraction) process, which is the standard and mature technology applied worldwide to recover uranium and plutonium from spent nuclear fuel at industrial scale. Following the dissolution of the spent fuel in nitric acid and the removal of uranium and plutonium ...
The plant used PUREX chemistry (based on tributyl phosphate (TBP)) to extract plutonium and uranium from used nuclear fuel originating primarily from Magnox reactors. [1] The plant was originally constructed and operated by the United Kingdom Atomic Energy Authority (UKAEA), but in 1971 control was transferred to British Nuclear Fuels Limited ...
The UREX process is a PUREX process which has been modified to prevent the plutonium being extracted. This can be done by adding a plutonium reductant before the first metal extraction step. In the UREX process, ~99.9% of the uranium and >95% of technetium are separated from each other and the other fission products and actinides. The key is ...
Purex is a brand of laundry detergent and laundry-related products manufactured by Henkel North American Consumer Goods and marketed in the United States and Canada. Purex is one of the most widely used laundry detergents in North America. Its original product, Purex Bleach, was a major competitor to Clorox bleach.
It is also used in nuclear reprocessing as part of the PUREX process. A 15–40% (usually about 30%) solution of tributyl phosphate in kerosene or dodecane is used in the liquid–liquid extraction (solvent extraction) of uranium, plutonium, and thorium from spent uranium nuclear fuel rods dissolved in nitric acid. Liquid extraction can also be ...
This type of hot cell is used purely for production of radiopharmaceuticals. A chemistry unit is placed in each cell, the production process is initiated (receiving the radioactive 18 F from the cyclotron) and once finished, the cells are left closed for a minimum of 6 hours allowing the radiation to decrease to a safe level. No manipulation is ...
It is possible, however, to remove the americium from the plutonium by a chemical separation process. Even under the worst conditions, the americium/plutonium mixture is less radioactive than a spent-fuel dissolution liquor, so it should be relatively straightforward to recover the plutonium by PUREX or another aqueous reprocessing method.