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Ammonium chloride precipitates and is removed by filtration, and the solution is recycled to produce more sodium carbonate. Hou's process eliminates the production of calcium chloride. The byproduct ammonium chloride can be refined, used as a fertilizer and may have greater commercial value than CaCl 2, thus reducing the extent of waste beds.
Ammonium carbonate is a chemical compound with the chemical formula [N H 4] 2 C O 3. It is an ammonium salt of carbonic acid. It is composed of ammonium cations [NH 4] + and carbonate anions CO 2− 3. Since ammonium carbonate readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as ...
Each ion can be either monatomic (termed simple ion), such as sodium (Na +) and chloride (Cl −) in sodium chloride, or polyatomic, such as ammonium (NH + 4) and carbonate (CO 2− 3) ions in ammonium carbonate. Salts containing basic ions hydroxide (OH −) or oxide (O 2−) are classified as bases, such as sodium hydroxide and potassium oxide.
In a laboratory, calcium carbonate can easily be crystallized from calcium chloride (CaCl 2), by placing an aqueous solution of CaCl 2 in a desiccator alongside ammonium carbonate [NH 4] 2 CO 3. [10] In the desiccator, ammonium carbonate is exposed to air and decomposes into ammonia , carbon dioxide, and water .
Ammonium chloride pyrolyses and reforms into ammonium-chloride smoke after cooling. Ammonium chloride appears to sublime upon heating but actually reversibly decomposes into ammonia and hydrogen chloride gas: [3] NH 4 Cl ⇌ NH 3 + HCl. Ammonium chloride reacts with a strong base, like sodium hydroxide, to release ammonia gas: NH 4 Cl + NaOH ...
Calcium chloride was apparently discovered in the 15th century but wasn't studied properly until the 18th century. [11] It was historically called "fixed sal ammoniac" (Latin: sal ammoniacum fixum [12]) because it was synthesized during the distillation of ammonium chloride with lime and was nonvolatile (while the former appeared to sublime); in more modern times (18th-19th cc.) it was called ...
For pH control, popular chemicals include calcium carbonate, calcium oxide, magnesium hydroxide, and sodium bicarbonate. The selection of an appropriate neutralization chemical depends on the particular application. There are many uses of neutralization reactions that are acid-alkali reactions. A very common use is antacid tablets.
One example is the reaction of mercury(II) chloride with ammonia (Calomel reaction) where the resulting mercuric amidochloride is highly insoluble. HgCl 2 + 2 NH 3 → HgCl(NH 2) + [NH 4]Cl. Ammonia is a Lewis base and a "pure" sigma donor. It is also compact such that steric effects are negligible.