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It consists of Cu + cations and acetylide anions − C≡C −, with the triple bond between the two carbon atoms. Although never characterized by X-ray crystallography, the material has been claimed at least since 1856. [2] One form is claimed to be a monohydrate with formula Cu 2 C 2 ·H 2 O. Copper(I) acetylide is a reddish-brown explosive ...
The carbide product produced generally contains around 80% calcium carbide by weight. The carbide is crushed to produce small lumps that can range from a few mm up to 50 mm. The impurities are concentrated in the finer fractions. The CaC 2 content of the product is assayed by measuring the amount of acetylene produced on hydrolysis. As an ...
In chemistry, an acetylide is a compound that can be viewed as the result of replacing one or both hydrogen atoms of acetylene (ethyne) HC≡CH by metallic or other cations. Calcium carbide is an important industrial compound, which has long been used to produce acetylene for welding and illumination. It is also a major precursor to vinyl ...
Barium carbide can be synthesized as an impure compound by reducing barium carbonate powder with metallic magnesium in the presence of carbon. [3] Barium carbide can also be made by reducing carbon dioxide with hot barium metal at 600°C. [4] These methods are used because of their high yield, and because the carbide is used to make acetylene.
Each lithium atom is surrounded by six carbon atoms from 4 different acetylide anions, with two acetylides co-ordinating side -on and the other two end-on. [3] [6] The relatively short C-C distance of 120 pm indicates the presence of a C≡C triple bond. At high temperatures Li 2 C 2 transforms reversibly to a cubic anti-fluorite structure. [7]
Silver acetylide is an inorganic chemical compound with the formula Ag 2 C 2, a metal acetylide. The compound can be regarded as a silver salt of the weak acid , acetylene . The salt's anion consists of two carbon atoms linked by a triple bond , thus, its structure is [Ag + ] 2 [ − C≡C − ] .
Strontium carbide (also more precisely known as strontium acetylide or strontium dicarbide) is a salt with chemical formula SrC 2. It was first synthesized by Moissan in 1894. [1] Strontium carbide can be formed in an electric arc furnace from strontium carbonate and a reductant, such as a reducing sugar [1] [2] or magnesium metal. [3]
The reaction proceeds via the intermediacy of copper(I) acetylides, which are then oxidized by the copper(II) acetate, releasing the acetylide radical. A related reaction involving copper acetylides is the synthesis of ynamines, terminal alkynes with amine groups using Cu 2 (OAc) 4. [15] It has been used for hydroamination of acrylonitrile. [16]
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