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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
While lists of noble metals can differ, they tend to cluster around gold and the six platinum group metals: ruthenium, rhodium, palladium, osmium, iridium, and platinum. In addition to this term's function as a compound noun , there are circumstances where noble is used as an adjective for the noun metal .
Pourbaix diagram of iron in uncomplexed media (anions other than OH-not considered). Ion concentration 0.001 m (mol/kg water). Temperature 25°C. Date: 23 October 2007: Source: self-made, with data from software FactSage version 5.3. Author: Metallos
English: Pourbaix diagram of vanadium. Date: 22 September 2007 (original upload date) Vectorized 2013-10-12 15:15:48 ... The following 4 pages use this file: Group 5 ...
Pourbaix Diagrams are thermodynamic charts constructed using the Nernst equation and visualize the relationship between possible phases of a system, bounded by lines representing the reactions that transport between them. They can be read much like a phase diagram. In 1963, Pourbaix produced "Atlas of Electrochemical Equilibria", which contains ...
Similar to Pourbaix diagrams for the speciation of redox species as a function of the redox potential and the pH, ionic partition diagrams indicate in which phase an acid or a base is predominantly present in a biphasic system as a function of the Galvani potential difference between the two phases and the pH of the aqueous solution.
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According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5. [1] The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonatate the cement in the concrete from the moment the object is made.