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(ch 3) 3 coh + hcl → (ch 3) 3 ccl + h 2 o Because tert -butanol is a tertiary alcohol, the relative stability of the tert -butyl carbocation in the step 2 allows the S N 1 mechanism to be followed, whereas a primary alcohol would follow an S N 2 mechanism.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: ... [2] Acetone: 0.78 56.2 1.67 –94.8 K b [3] Benzene: 0.87 80. ...
H 2 C=CH 2 + HCl → CH 3 CH 2 Cl. In oxychlorination, hydrogen chloride instead of the more expensive chlorine is used for the same purpose: CH 2 =CH 2 + 2 HCl + 1 ⁄ 2 O 2 → ClCH 2 CH 2 Cl + H 2 O. Secondary and tertiary alcohols react with hydrogen chloride to give the corresponding chlorides.
Boiling point: 68.3 to 69.3 °C; 154.8 to 156.7 °F; 341.4 to 342.4 K ... 2.486 Henry's law constant (k H) 630 nmol Pa −1 kg −1: Refractive index ... (1-chloro-2 ...
Isobutyl chloride (1-chloro-2-methylpropane) tert-Butyl chloride (2-chloro-2-methylpropane) This page was last edited on 25 November ...
tert-Amyl chloride (2-methyl-2-butyl chloride) is an alkyl chloride used for flavoring and odorizing. [2] At room temperature, it is a colorless liquid with an unpleasant odor. It is an isomer of 1-chloropentane ( n -amyl chloride).
Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.