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The energy difference of 94.3 kJ/mol between ground state and singlet oxygen corresponds to a forbidden singlet-triplet transition in the near-infrared at ~1270 nm. [12] As a consequence, singlet oxygen in the gas phase is relatively long lived (54-86 milliseconds), [ 13 ] although interaction with solvents reduces the lifetime to microseconds ...
Molecular orbital diagrams are diagrams of molecular orbital (MO) energy levels, shown as short horizontal lines in the center, flanked by constituent atomic orbital (AO) energy levels for comparison, with the energy levels increasing from the bottom to the top. Lines, often dashed diagonal lines, connect MO levels with their constituent AO levels.
The energy level of the bonding orbitals is lower, and the energy level of the antibonding orbitals is higher. For the bond in the molecule to be stable, the covalent bonding electrons occupy the lower energy bonding orbital, which may be signified by such symbols as σ or π depending on the situation.
Within a particular representation, the symmetry-adapted atomic orbitals mix more if their atomic energy levels are closer. The general procedure for constructing a molecular orbital diagram for a reasonably simple molecule can be summarized as follows: 1. Assign a point group to the molecule. 2. Look up the shapes of the SALCs. 3.
Triatomic oxygen (ozone, O 3) is a very reactive allotrope of oxygen that is a pale blue gas at standard temperature and pressure. Liquid and solid O 3 have a deeper blue color than ordinary O 2, and they are unstable and explosive. [5] [6] In its gas phase, ozone is destructive to materials like rubber and fabric and is damaging to lung tissue ...
Oxygen gas is the second most common component of the Earth's atmosphere, taking up 20.8% of its volume and 23.1% of its mass (some 10 15 tonnes). [19] [70] [d] Earth is unusual among the planets of the Solar System in having such a high concentration of oxygen gas in its atmosphere: Mars (with 0.1% O 2 by volume) and Venus have much less. The O
The energy associated to an electron is that of its orbital. The energy of a configuration is often approximated as the sum of the energy of each electron, neglecting the electron-electron interactions. The configuration that corresponds to the lowest electronic energy is called the ground state. Any other configuration is an excited state.
The changes between these levels are called "transitions" and are plotted on the Jablonski diagram. Radiative transitions involve either the absorption or emission of a photon. As mentioned above, these transitions are denoted with solid arrows with their tails at the initial energy level and their tips at the final energy level.