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Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes as a solvate with ligands bound to Na +. [1]
Naphthalene is an organic compound with formula C 10 H 8. It is the simplest polycyclic aromatic hydrocarbon, and is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. [15] As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings.
1-Naphthol, or α-naphthol, is an organic compound with the formula C 10 H 7 OH. It is a fluorescent white solid. 1-Naphthol differs from its isomer 2-naphthol by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol. Both isomers are soluble in simple organic solvents. They are ...
The naphthalene route (the Gibbs phthalic anhydride process or the Gibbs–Wohl naphthalene oxidation reaction) has declined relative to the o-xylene route. Proposed early steps in vanadium -catalyzed oxidation of naphthalene to phthalic anhydride, with V 2 O 5 represented as a molecule versus its true extended structure.
It is almost insoluble in cold water, slightly soluble in petroleum ether, and more soluble in polar organic solvents. In alkaline solutions it produces a reddish-brown color. Vitamin K is a derivative of 1,4-naphthoquinone. It is a planar molecule with one aromatic ring fused to a quinone subunit. [2] It is an isomer of 1,2-naphthoquinone.
Naphthalene-2-sulfonic acid undergoes many reactions, some of which are or were of commercial interest. Fusion with sodium hydroxide followed by acidification gives 2-naphthol. It is an intermediate in the formation of 2,6-, 2,7- and 1,6-naphthalene disulfonic acids as well as 1,3,6-naphthalenetrisulfonic acid.
The pK a of 2-hydroxyazulene in water is 8.71. It is more acidic than phenol or naphthol. The pK a of 6-hydroxyazulenes in water is 7.38 making it also more acidic than phenol or naphthol. [17] In naphth[a]azulene, a naphthalene ring is condensed at the 1,2-positions of azulene.
Chemical structure of 1,4-naphthoquinone. Naphthoquinones constitute a class of organic compounds structurally related to naphthalene. Two isomers are common for the parent naphthoquinones: 1,2-Naphthoquinone; 1,4-Naphthoquinone