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The alpha phase of zirconium phosphate is under the P21/n space group, with cell dimensions of a = 9.060 Å, b = 5.297 Å, c = 15.414 Å, α = γ = 90°, β = 101.71° and Z = 4.21 The basal interlayer distance for the α-Zirconium phosphate is 7.6 Å, where 6.6 Å is the layer thickness and the remaining 1 Å space is occupied by the ...
Zirconium cladding rapidly reacts with water steam above 1,500 K (1,230 °C). [15] [16] Oxidation of zirconium by water is accompanied by release of hydrogen gas. This oxidation is accelerated at high temperatures, e.g. inside a reactor core if the fuel assemblies are no longer completely covered by liquid water and insufficiently cooled. [17]
Zirconium diphosphide forms grey crystals that is insoluble in water. Zirconium diphosphide is very toxic. [3] Has a lead(II) chloride crystal structure. [4] [2] [5] It dissolves in warm concentrated sulfuric acid. It decomposes into phosphorus and ZrP when heated in vacuum: [6] ZrP 2 → ZrP + P
The term Widmanstätten structure is also used on non-meteoritic material to indicate a structure with a geometrical pattern resulting from the formation of a new phase along certain crystallographic planes of the parent phase, such as the basketweave structure in some zirconium alloys. The Widmanstätten structures form due to the growth of ...
The "backbone" of a polyphosphoric acid molecule is a chain of alternating P and O atoms. Each extra orthophosphoric unit that is condensed adds 1 extra H atom, 1 extra P atom, and 3 extra O atoms. The general formula of a polyphosphoric acid is H n+2 P n O 3n+1 or HO[−P(O)(OH)−O−] n H.
Freeze-cast alumina that has been partially sintered. The freezing direction in the image is up. Freeze-casting, also frequently referred to as ice-templating, freeze casting, or freeze alignment, is a technique that exploits the highly anisotropic solidification behavior of a solvent (generally water) in a well-dispersed solution or slurry to controllably template directionally porous ...
[1] Organozirconium chemistry is the science of exploring the properties, structure, and reactivity of organozirconium compounds, which are organometallic compounds containing chemical bonds between carbon and zirconium. [2] Organozirconium compounds have been widely studied, in part because they are useful catalysts in Ziegler-Natta ...
Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP. [1] [2] [3] Preparation.