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Hexamethylenediamine or hexane-1,6-diamine, is the organic compound with the formula H 2 N(CH 2) 6 NH 2. The molecule is a diamine, consisting of a hexamethylene hydrocarbon chain terminated with amine functional groups. The colorless solid (yellowish for some commercial samples) has a strong amine odor.
A colorless oily liquid with a pungent odor, it is soluble in hydrocarbons and ethers. Sebacoyl chloride is corrosive; like all acyl chlorides, it hydrolyzes, evolving hydrogen chloride. It is less susceptible to hydrolysis though than shorter chain aliphatic acyl chlorides. [1]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
It is a clear brown liquid. It reacts with water to give adipic acid. It is prepared by treatment of adipic acid with thionyl chloride. [1] Adipoyl chloride reacts with hexamethylenediamine to form nylon 6,6. [2]
in which c i is the molar concentration of functional groups in the ith component of a monomer or polymer, t is the elapsed time, y is a coordinate normal to the surface/interface, D i is the molecular diffusion coefficient of the functional groups of interest, and J i is the thermodynamic rate of reaction. [9]
Nylon 66 (loosely written nylon 6-6, nylon 6/6, nylon 6,6, or nylon 6:6) is a type of polyamide or nylon. It, and nylon 6 , are the two most common for textile and plastic industries. Nylon 66 is made of two monomers each containing 6 carbon atoms, hexamethylenediamine and adipic acid , which give nylon 66 its name. [ 1 ]
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1,6-Hexanediol can improve the hardness and flexibility of polyesters as it contains a fairly long hydrocarbon chain. In polyurethanes, it is used as a chain extender , and the resulting modified polyurethane has high resistance to hydrolysis as well as mechanical strength, but with a low glass transition temperature.