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The detection limit (according to IUPAC) is the smallest concentration, or the smallest absolute amount, of analyte that has a signal statistically significantly larger than the signal arising from the repeated measurements of a reagent blank. Mathematically, the analyte's signal at the detection limit is given by:
A blank value in analytical chemistry is a measurement of a blank. The reading does not originate from a sample, but the matrix effects , reagents and other residues . These contribute to the sample value in the analytical measurement and therefore have to be subtracted.
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
Analyse-it is a statistical analysis add-in for Microsoft Excel. Analyse-it is the successor to Astute, developed in 1992 for Excel 4 and the first statistical analysis add-in for Microsoft Excel. Analyse-it is the successor to Astute, developed in 1992 for Excel 4 and the first statistical analysis add-in for Microsoft Excel.
A blank solution is a solution containing little to no analyte of interest, [1] usually used to calibrate instruments such as a colorimeter. According to the EPA, the "primary purpose of blanks is to trace sources of artificially introduced contamination." [2] Different types of blanks are used to identify the source of contamination in the ...
The 95% limits of agreement can be unreliable estimates of the population parameters especially for small sample sizes so, when comparing methods or assessing repeatability, it is important to calculate confidence intervals for 95% limits of agreement. This can be done by Bland and Altman's approximate method [3] or by more precise methods. [6]
Note that the limits widen for each successive rational subgroup, approaching ^. [ 2 ] : 407 The EWMA chart is sensitive to small shifts in the process mean, but does not match the ability of Shewhart-style charts (namely the x ¯ {\displaystyle {\bar {x}}} and R and x ¯ {\displaystyle {\bar {x}}} and s charts ) to detect larger shifts.
In statistical quality control, the CUSUM (or cumulative sum control chart) is a sequential analysis technique developed by E. S. Page of the University of Cambridge.It is typically used for monitoring change detection. [1]