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One gram of 100% active chlorine bleach has the same bleaching power as one gram of elemental chlorine. The most common chlorine-based bleaches are: Sodium hypochlorite (NaClO), usually as a 3–6% solution in water, usually called "liquid bleach" or just "bleach". Historically called "Javel water" (French: eau de Javel).
The hypochlorite can be in the form of a powder or a liquid such as chlorine bleach (solution of sodium hypochlorite or calcium hypochlorite in water). Water that is being shock chlorinated should not be swum in or drunk until the sodium hypochlorite count in the water goes down to three parts per million (ppm) or until the calcium hypochlorite ...
[47] [48] It may be made by diluting household bleach as appropriate (normally 1 part bleach to 9 parts water). [49] Such solutions have been demonstrated to inactivate both C. difficile [47] and HPV. [50] "Weak chlorine solution" is a 0.05% solution of hypochlorite used for washing hands, but is normally prepared with calcium hypochlorite ...
The hypochlorite anion and chlorine are in equilibrium in water; the position of the equilibrium is pH dependent and low pH (acidic) favors chlorine, [11] Cl 2 + H 2 O ⇌ 2H + + Cl − + ClO −. A hypochlorite bleach can react violently with hydrogen peroxide and produce oxygen gas: H 2 O 2 (aq) + NaOCl (aq) → NaCl (aq) + H 2 O(l) + O 2 (g)
The resulting liquid, known as "Eau de Javel" ("Javel water"), was a weak solution of sodium hypochlorite. Another strong chlorine oxidant and bleach which he investigated and was the first to produce, potassium chlorate (KClO 3), is known as Berthollet's Salt. Berthollet first determined the elemental composition of the gas ammonia, in 1785.
When acids are added to aqueous salts of hypochlorous acid (such as sodium hypochlorite in commercial bleach solution), the resultant reaction is driven to the left, and chlorine gas is formed. Thus, the formation of stable hypochlorite bleaches is facilitated by dissolving chlorine gas into basic water solutions, such as sodium hydroxide.
Evaporation under reduced pressure allows it to be concentrated further to about 40%, but then it decomposes to perchloric acid, chlorine, oxygen, water, and chlorine dioxide. Its most important salt is sodium chlorate, mostly used to make chlorine dioxide to bleach paper pulp. The decomposition of chlorate to chloride and oxygen is a common ...
Hypochlorite salts formed by the reaction between chlorine and alkali and alkaline earth metal hydroxides. The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2).