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In order to flatten the steep learning curve aqion provides an introduction to fundamental water-related topics in form of a "chemical pocket calculator". Second. The program mediates between two terminological concepts: The calculations are performed in the "scientific realm" of thermodynamics (activities, speciation, log K values, ionic ...
The Born–Landé equation is a means of calculating the lattice energy of a crystalline ionic compound. In 1918 [ 1 ] Max Born and Alfred Landé proposed that the lattice energy could be derived from the electrostatic potential of the ionic lattice and a repulsive potential energy term.
In physics, the Saha ionization equation is an expression that relates the ionization state of a gas in thermal equilibrium to the temperature and pressure. [ 1 ] [ 2 ] The equation is a result of combining ideas of quantum mechanics and statistical mechanics and is used to explain the spectral classification of stars.
where z is the electrical charge on the ion, I is the ionic strength, ε and b are interaction coefficients and m and c are concentrations. The summation extends over the other ions present in solution, which includes the ions produced by the background electrolyte. The first term in these expressions comes from Debye–Hückel theory.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel . It describes how the electrical current through an electrode depends on the voltage difference between the electrode and the bulk electrolyte for a simple, unimolecular redox reaction.
Proteins purification and separation can be performed by precipitation in changing the nature of the solvent or the value of its relative permittivity (e.g., by replacing water by ethanol), or by increasing the ionic strength of the solution.
The cycle is concerned with the formation of an ionic compound from the reaction of a metal (often a Group I or Group II element) with a halogen or other non-metallic element such as oxygen. Born–Haber cycles are used primarily as a means of calculating lattice energy (or more precisely enthalpy [ note 1 ] ), which cannot otherwise be ...
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