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Four quantum numbers can describe an electron energy level in a hydrogen-like atom completely: Principal quantum number (n) Azimuthal quantum number (ℓ) Magnetic quantum number (m ℓ) Spin quantum number (m s) These quantum numbers are also used in the classical description of nuclear particle states (e.g. protons and neutrons).
The associated quantum number is the main total angular momentum quantum number j. It can take the following range of values, jumping only in integer steps: [ 1 ] | ℓ − s | ≤ j ≤ ℓ + s {\displaystyle \vert \ell -s\vert \leq j\leq \ell +s} where ℓ is the azimuthal quantum number (parameterizing the orbital angular momentum) and s is ...
the quantum numbers j, m are often labelled next to the arrows to refer to a specific angular momentum state, arrowheads are almost always placed at the middle of the line, rather than at the tip, equals signs "=" are placed between equivalent diagrams, exactly like for multiple algebraic expressions equal to each other.
This is a table of Clebsch–Gordan coefficients used for adding angular momentum values in quantum mechanics.The overall sign of the coefficients for each set of constant , , is arbitrary to some degree and has been fixed according to the Condon–Shortley and Wigner sign convention as discussed by Baird and Biedenharn. [1]
The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment
Instead, it is replaced by the following weaker rule: = for any angular-momentum-like quantum number k. Nonetheless, a combination of j i and m i is always an integer, so the stronger rule applies for these combinations: ( − 1 ) 2 ( j i − m i ) = 1 {\displaystyle (-1)^{2(j_{i}-m_{i})}=1} This identity also holds if the sign of either j i or ...
Other magnetic quantum numbers are similarly defined, such as m j for the z-axis component the total electronic angular momentum j, [1] and m I for the nuclear spin I. [2] Magnetic quantum numbers are capitalized to indicate totals for a system of particles, such as M L or m L for the total z-axis orbital angular momentum of all the electrons ...
The classical definition of angular momentum is =.The quantum-mechanical counterparts of these objects share the same relationship: = where r is the quantum position operator, p is the quantum momentum operator, × is cross product, and L is the orbital angular momentum operator.
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