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When comparing a polar and nonpolar molecule with similar molar masses, the polar molecule in general has a higher boiling point, because the dipole–dipole interaction between polar molecules results in stronger intermolecular attractions. One common form of polar interaction is the hydrogen bond, which is also
Molecules with a polar surface area of greater than 140 angstroms squared (Å 2) tend to be poor at permeating cell membranes. [1] For molecules to penetrate the blood–brain barrier (and thus act on receptors in the central nervous system ), a PSA less than 90 Å 2 is usually needed.
Vapor phases represent the simplest non polar phases, because it has no interaction with the solute. [18] The hydration potential and its correlation to the appearance of amino acids on the surface of proteins was studied by Wolfenden. Aqueous and polymer phases were used in the development of a novel partitioning scale. [19]
Its principal utility is that it provides simple predictions of phase equilibrium based on a single parameter that is readily obtained for most materials. These predictions are often useful for nonpolar and slightly polar (dipole moment < 2 debyes [citation needed]) systems without hydrogen bonding. It has found particular use in predicting ...
Accessible surface area is often used when calculating the transfer free energy required to move a biomolecule from an aqueous solvent to a non-polar solvent, such as a lipid environment. The LCPO method is also used when calculating implicit solvent effects in the molecular dynamics software package AMBER .
The reference point (analogous to the origin of a Cartesian coordinate system) is called the pole, and the ray from the pole in the reference direction is the polar axis. The distance from the pole is called the radial coordinate, radial distance or simply radius, and the angle is called the angular coordinate, polar angle, or azimuth. [1]
The rivalry between No. 6 Notre Dame and No. 17 Army is back and it has major playoff implications.. The Fighting Irish (9-1) and the Black Knights (9-0) will face off against each other at Yankee ...
If two lines a and k pass through a single point Q, then the polar q of Q joins the poles A and K of the lines a and k, respectively. The concepts of a pole and its polar line were advanced in projective geometry. For instance, the polar line can be viewed as the set of projective harmonic conjugates of a given point, the pole, with respect to ...