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In terms of Lewis structures, formal charge is used in the description, comparison, and assessment of likely topological and resonance structures [7] by determining the apparent electronic charge of each atom within, based upon its electron dot structure, assuming exclusive covalency or non-polar bonding.
All charge-neutral boron halides violate the octet rule, hence they typically are Lewis acidic. For example, boron trifluoride (BF 3) combines eagerly with fluoride sources to give the tetrafluoroborate anion, BF 4 −. Boron trifluoride is used in the petrochemical industry as a catalyst. The halides react with water to form boric acid. [51]
Various representations of bonding in borenium ions. [2]A borenium ion is an inorganic cation with the chemical formula [BR 2 L] +In this class of molecules, the electron-deficient boron center has two valence electrons involved in sigma bonding with two ligands, while the third ligand is a two-electron donor such that the overall charge of the complex is +1. [1]
For example, in the formation of an ammonium ion from ammonia and hydrogen the ammonia molecule donates a pair of electrons to the proton; [11] the identity of the electrons is lost in the ammonium ion that is formed. Nevertheless, Lewis suggested that an electron-pair donor be classified as a base and an electron-pair acceptor be classified as ...
As anticipated by its hydride clusters, boron forms a variety of stable compounds with formal oxidation state less than three. B 2 F 4 and B 4 Cl 4 are well characterized. [6] Ball-and-stick model of superconductor magnesium diboride. Boron atoms lie in hexagonal aromatic graphite-like layers, with a charge of −1 on each boron atom.
The structure of the repeating unit of the octaborate ion ([B 8 O 13] 2−) in the alpha form of disodium octaborate (α-Na 2 [B 8 O 13]). [5] This anion is cyclic and polymeric. It has a tetrahedral molecular geometry at the negatively charged boron atoms and a trigonal planar molecular geometry at the neutral boron atoms.
A diagram showing the bond dipole moments of boron trifluoride. δ- shows an increase in negative charge and δ+ shows an increase in positive charge. Note that the dipole moments drawn in this diagram represent the shift of the valence electrons as the origin of the charge, which is opposite the direction of the actual electric dipole moment.
A charge number also can help when drawing Lewis dot structures. For example, if the structure is an ion, the charge will be included outside of the Lewis dot structure. Since there is a negative charge on the outside of the Lewis dot structure, one electron needs to be added to the structure.