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Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
The dehydrogenation of 2-butanol is catalysed by copper, zinc, or bronze: CH 3 CH(OH)CH 2 CH 3 → CH 3 C(O)CH 2 CH 3 + H 2. This is used to produce approximately 700 million kilograms yearly. Other syntheses that have been examined but not implemented include Wacker oxidation of 2-butene and oxidation of isobutylbenzene, which is analogous to ...
2-Phenyl-2-propanol can either be applied in organic syntheses, or be reactants or intermediates in agrochemical, medical, and dyestuff fields. [ 2 ] 2-Phenyl-2-propanol is the main metabolite of cumene , and therefore 2-phenyl-2-propanol can serve as a biomarker of cumene.
Butan-2-yl (sec-butyl) group is chiral. The carbon atom at position 2 is a stereocenter. It has four different groups attached: −H, −CH 3, −CH 2 −CH 3, and −R (the R group is not equal to those three groups). The names of the two chiral groups are: (2S)-butan-2-yl and (2R)-butan-2-yl.
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Isobutanol (IUPAC nomenclature: 2-methylpropan-1-ol) is an organic compound with the formula (CH 3) 2 CHCH 2 OH (sometimes represented as i-BuOH). This colorless, flammable liquid with a characteristic smell is mainly used as a solvent either directly or as its esters.
Like other butanols, butan-2-ol has low acute toxicity. The LD 50 is 4400 mg/kg (rat, oral). [6]Several explosions have been reported [7] [8] [9] during the conventional distillation of 2-butanol, apparently due to the buildup of peroxides with the boiling point higher than that of pure alcohol (and therefore concentrating in the still pot during distillation).