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Carboxylates bind to single metals by one or both oxygen atoms, the respective notation being κ 1 - and κ 2-.In terms of electron counting, κ 1-carboxylates are "X"-type ligands, i.e., a pseudohalide-like. κ 2-carboxylates are "L-X ligands", i.e. resembling the combination of a Lewis base (L) and a pseudohalide (X).
A synthetic element is one of 24 known chemical elements that do not occur naturally on Earth: they have been created by human manipulation of fundamental particles in a nuclear reactor, a particle accelerator, or the explosion of an atomic bomb; thus, they are called "synthetic", "artificial", or "man-made". The synthetic elements are those ...
Metals react with acids to form salts and hydrogen gas. Liberation of hydrogen gas when zinc reacts with hydrochloric acid. + () + [2] [3] However less reactive metals can not displace the hydrogen from acids. [3] (They may react with oxidizing acids though.)
Medicine: Organic synthesis plays a vital role in drug discovery, allowing chemists to develop and optimize new drugs by modifying organic molecules. [9] Additionally, the synthesis of metal complexes for medical imaging and cancer treatments is a key application of chemical synthesis, enabling advanced diagnostic and therapeutic techniques. [10]
Enantioselective synthesis, also called asymmetric synthesis, [1] is a form of chemical synthesis.It is defined by IUPAC as "a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric (enantiomeric or diastereomeric) products in unequal amounts."
Examples from industry are the reduction of phthalic acid: and the reduction of 2-methoxynaphthalene: The Tafel rearrangement, named for Julius Tafel, was at one time an important method for the synthesis of certain hydrocarbons from alkylated ethyl acetoacetate, a reaction accompanied by the rearrangement reaction of the alkyl group: [15] [16]
Elements with low electronegativities, such as most metals, easily donate electrons and oxidize – they are reducing agents. On the contrary, many oxides or ions with high oxidation numbers of their non-oxygen atoms, such as H 2 O 2, MnO − 4, CrO 3, Cr 2 O 2− 7, or OsO 4, can gain one or two extra electrons and are strong oxidizing agents.
The term transmutation dates back to alchemy.Alchemists pursued the philosopher's stone, capable of chrysopoeia – the transformation of base metals into gold. [3] While alchemists often understood chrysopoeia as a metaphor for a mystical or religious process, some practitioners adopted a literal interpretation and tried to make gold through physical experimentation.