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In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Ammonia is moderately basic; a 1.0 M aqueous solution has a pH of 11.6, and if a strong acid is added to such a solution until the solution is neutral (pH = 7), 99.4% of the ammonia molecules are protonated. Temperature and salinity also affect the proportion of ammonium [NH 4] +.
When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: H 2 O + NH 3 ⇌ OH − + [NH 4] + The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are converted into ammonium ions.
Heating at higher temperatures results in decomposition into ammonia, nitrogen, sulfur dioxide, and water. [17] As a salt of a strong acid (H 2 SO 4) and weak base (NH 3), its solution is acidic; the pH of 0.1 M solution is 5.5. In aqueous solution the reactions are those of NH + 4 and SO 2−
The pH of the ocean tends to be about 8.1 which means that ammonium is more abundant than ammonia, however, when the pH increases, as it does when primary production rates are high, ammonia becomes more abundant. This also means that there are more toxic effects than in freshwater that can be more acidic.
Ammonium fluoride sublimes when heated—a property common among ammonium salts. In the sublimation, the salt decomposes to ammonia and hydrogen fluoride; the two gases can still recombine, i.e. the reaction is reversible: [NH 4]F ⇌ NH 3 + HF
log 10 of anydrous ammonia vapor pressure. Uses formula shown below. Vapor-pressure formula for ammonia: [4] log 10 P = A – B / (T − C),
Ammonium hydroxide is commonly used but it doesn't seem to be an accurate name. There is only a small fraction of ammonium ions and hydroxide ions in NH3(aq). I think ammonia solution is more appropriate as the title. In google, "ammonium hydroxide" and "ammonia solution" have similar popularity. Both of them have more than 600,000 links.