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Additionally, specific physical and mechanical properties of coal and particular carbonization properties The calorific value Q of coal [kJ/kg] is the heat liberated by its complete combustion with oxygen. Q is a complex function of the elemental composition of the coal [citation needed]. Q can be determined experimentally using calorimeters.
Anthracite, also known as hard coal and black coal, is a hard, compact variety of coal that has a submetallic lustre. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the highest ranking of coals.
The rank of coal is correlated with its geologic history, as described in Hilt's law. In the ASTM system, any coal with more than 69% fixed carbon is classified by its content of carbon and volatiles. Coal with less than 69% fixed carbon is classified by its heating value. Volatiles and carbon are on a dry mineral free base; heating value is ...
Smokeless fuels generally have a high calorific value, with that of anthracite being greater than dry wood for example, and many smokeless briquettes are made from this type of coal. Thus anthracite has a calorific value of 32.5 MJ/kg compared with that of dry wood of about 21 MJ/kg.
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Young coals (brown coal, lignite) are not black. The two main black coals are bituminous, which is more abundant, and anthracite. The % carbon in coal follows the order anthracite > bituminous > lignite > brown coal. The fuel value of coal varies in the same order. Some anthracite deposits contain pure carbon in the form of graphite.
All values refer to 25 °C and to the thermodynamically stable standard state at that temperature unless noted. Values from CRC refer to "100 kPa (1 bar or 0.987 standard atmospheres)". Lange indirectly defines the values to be standard atmosphere of "1 atm (101325 Pa)", although citing the same NBS and JANAF sources among others.
Diesel fuel has an HHV value of 44.80 MJ/kg and anthracite coal a value of 32.50 MJ/kg. Moisture and ash-free firewood has a lower value of 21.70 MJ/kg while dry peat has the lowest value of all common fuels of about 15.00 MJ/kg. These are somewhat ideal values and the actual heat realized by any fuel will depend on the fireplace or combustion ...