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2-Bromo-1-chloropropane, C 3 H 6 BrCl, is an alkyl halide. This simple compound has a chiral center and is used sometimes to determine the enantiomeric resolution of simple chromatographic methods. References
2-Bromopropane, also known as isopropyl bromide and 2-propyl bromide, is the halogenated hydrocarbon with the formula CH 3 CHBrCH 3. It is a colorless liquid. It is a colorless liquid. It is used for introducing the isopropyl functional group in organic synthesis . 2-Bromopropane is prepared by heating isopropanol with hydrobromic acid .
Chiral recognition implies the ability of chiral stationery phases to interact differently with mirror-image molecules, leading to their separation. The mechanism of enantiomeric resolution using CSPs is generally attributed to the “three-point" interaction model (fig.1.) between the analyte and the chiral selector in the stationary phase.
Chiral molecules can differ in their chemical properties, but are identical in their physical properties, which can make distinguishing enantiomers challenging. Absolute configurations for a chiral molecule (in pure form) are most often obtained by X-ray crystallography , although with some important limitations.
1,2-Dibromo-3-chloropropane (dibromochloropropane), better known as DBCP, is the organic compound with the formula BrCH(CH 2 Br)(CH 2 Cl). It is a dense colorless liquid although commercial samples often appear amber or even brown. It is the active ingredient in the nematicide Nemagon, also known as Fumazone.
1-Bromo-3-chloropropane is an organohalogen compound with the formula Br(CH 2) 3 Cl. It is a colorless liquid, produced by free-radical addition of hydrogen bromide to allyl chloride. [1] It is used as an alkylating agent to install the –(CH 2) 3 Cl [2] [3] and –(CH 2) 3 – groups. [4] For example, it is a precursor to 4-chlorobutyronitrile.
Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.
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