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David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition.CRC Press. Boca Raton, Florida, 2003; Section 6, Fluid Properties; Vapor Pressure Uncertainties of several degrees should generally be assumed.
This is illustrated in the vapor pressure chart (see right) that shows graphs of the vapor pressures versus temperatures for a variety of liquids. [7] At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [ 1 ] 760 Torr, 101.325 kPa, or 14.69595 psi.
of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p: 0.212 J/(mol K) at −200°C Liquid properties Std enthalpy change of formation, Δ f H o liquid: −318.2 kJ/mol Standard molar entropy, S o liquid: 180 J/(mol K) Heat capacity, c p: 2.68 J/(gK) at 20°C-25°C Gas properties Std enthalpy ...
Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures: log 10 (P) = −(0.05223) a / T + b , where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
Table data obtained from CRC Handbook of Chemistry and Physics, 44th ed. log e of Glycerol vapor pressure. Uses formula: log e P k P a = {\displaystyle \scriptstyle \log _{e}P_{kPa}=} A × l n ( T ) + B / T + C + D × T 2 {\displaystyle \scriptstyle A\times ln(T)+B/T+C+D\times T^{2}} with coefficients A=-2.125867E+01, B=-1.672626E+04, C=1. ...
of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid-147.6 kJ/mol Standard molar entropy, S o liquid: 229.7 J/(mol K) Heat capacity, c p: 132.42 J/(mol K) –262 °C to –3 °C Gas properties Std enthalpy change of ...
of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid –271.2 kJ/mol Standard molar entropy, S o liquid: 253.5 J/(mol K) Enthalpy of combustion, Δ c H o –2726.3 kJ/mol Heat capacity, c p: 172.0 J/(mol K) Gas ...
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds