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[1] [2] In physical and analytical chemistry, infrared spectroscopy (IR spectroscopy) is a technique used to identify chemical compounds based on the way infrared radiation is absorbed by the compound. The absorptions in this range do not apply only to bonds in organic molecules.
Isoborneol is a bicyclic organic compound and a terpene derivative. The hydroxyl group in this compound is placed in an exo position. The endo diastereomer is called borneol .
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify ...
The FT-IR spectra were recorded using a Nicolet 170SX or a JASCO FT/IR-410 spectrometer. For spectra recorded in the Nicolet spectrometer, the data were stored at intervals of 0.5 cm −1 in the 4,000 – 2,000 cm −1 region and of 0.25 cm −1 in the 2,000 – 400 cm −1 region and the spectral resolution was 0.25 cm −1.
Industrially, a racemic mixture of camphor is used, leading to a racemic mixture of borneol and isoborneol. The chirality can be controlled by changing the chirality of camphor: (+)-camphor gives (−)-isoborneol and (+)-borneol. [7] Reduction of camphor with sodium borohydride (fast and irreversible) gives instead the diastereomer isoborneol.
Far infrared (FIR) or long wave refers to a specific range within the infrared spectrum of electromagnetic radiation. It encompasses radiation with wavelengths ranging from 15 μm (micrometers) to 1 mm, which corresponds to a frequency range of approximately 20 THz to 300 GHz. This places far infrared radiation within the CIE IR-B and IR-C ...
The Fourier transform with respect to provides the excitation spectrum (frequency ). Two-dimensional infrared spectroscopy (2D IR) is a nonlinear infrared spectroscopy technique that has the ability to correlate vibrational modes in condensed-phase systems. This technique provides information beyond linear infrared spectra, by spreading the ...
Based on the T–S diagram, the lowest energy transition is 4 T 1 to 4 T 2, which is seen in the near IR and is not observed in the visible spectrum. The main peak is the energy transition 4 T 1 (F) to 4 T 1 (P), and the slightly higher energy transition (the shoulder) is predicted to be 4 T 1 to 4 A 2 .