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The calculation of the sequence , …, is known as Gram–Schmidt orthogonalization, and the calculation of the sequence , …, is known as Gram–Schmidt orthonormalization. To check that these formulas yield an orthogonal sequence, first compute u 1 , u 2 {\displaystyle \langle \mathbf {u} _{1},\mathbf {u} _{2}\rangle } by substituting the ...
The carboxylic acid Schmidt reaction starts with acylium ion 1 obtained from protonation and loss of water. Reaction with hydrazoic acid forms the protonated azido ketone 2 , which goes through a rearrangement reaction with the alkyl group R, migrating over the C-N bond with expulsion of nitrogen.
In linear algebra, orthogonalization is the process of finding a set of orthogonal vectors that span a particular subspace.Formally, starting with a linearly independent set of vectors {v 1, ... , v k} in an inner product space (most commonly the Euclidean space R n), orthogonalization results in a set of orthogonal vectors {u 1, ... , u k} that generate the same subspace as the vectors v 1 ...
In other words, the sequence is obtained from the sequence of monomials 1, x, x 2, … by the Gram–Schmidt process with respect to this inner product. Usually the sequence is required to be orthonormal , namely, P n , P n = 1 , {\displaystyle \langle P_{n},P_{n}\rangle =1,} however, other normalisations are sometimes used.
In numerical linear algebra, the Arnoldi iteration is an eigenvalue algorithm and an important example of an iterative method.Arnoldi finds an approximation to the eigenvalues and eigenvectors of general (possibly non-Hermitian) matrices by constructing an orthonormal basis of the Krylov subspace, which makes it particularly useful when dealing with large sparse matrices.
[1] [2] [3] If both the donor and acceptor are sugars, then the product is an oligosaccharide. The reaction requires activation with a suitable activating reagent. The reactions often result in a mixture of products due to the creation of a new stereogenic centre at the anomeric position of the glycosyl donor.
Jørgen Pedersen Gram (27 June 1850 – 29 April 1916) was a Danish actuary and mathematician who was born in Nustrup, Duchy of Schleswig, Denmark and died in Copenhagen, Denmark. Important papers of his include On series expansions determined by the methods of least squares , and Investigations of the number of primes less than a given number .
In geology, a rock composed of different minerals may be a compositional data point in a sample of rocks; a rock of which 10% is the first mineral, 30% is the second, and the remaining 60% is the third would correspond to the triple [0.1, 0.3, 0.6]. A data set would contain one such triple for each rock in a sample of rocks.