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A pyrite cube (center) has dissolved away from a host rock, leaving behind trace gold. Iron pyrite is unstable when exposed to the oxidizing conditions prevailing at the Earth's surface: iron pyrite in contact with atmospheric oxygen and water, or damp, ultimately decomposes into iron oxyhydroxides (ferrihydrite, FeO(OH)) and sulfuric acid (H 2 ...
Iron formations can be divided into subdivisions known as: banded iron formations (BIFs) and granular iron formations (GIFs). [ 3 ] The above classification scheme is the most commonly used and accepted, though sometimes an older system is used which divides iron-rich sedimentary rocks into three categories: bog iron deposits , ironstones , and ...
The group is named for its most common member, pyrite (fool's gold), which is sometimes explicitly distinguished from the group's other members as iron pyrite. Pyrrhotite (magnetic pyrite) is magnetic, and is composed of iron and sulfur, but it has a different structure and is not in the pyrite group.
After being exposed to air and water, oxidation of metal sulfides (often pyrite, which is iron-sulfide) within the surrounding rock and overburden generates acidity. Colonies of bacteria and archaea greatly accelerate the decomposition of metal ions, although the reactions also occur in an abiotic environment.
The Gunflint Iron Formation is a banded iron formation, composed predominantly of dense chert and slate layers interbedded with ankerite carbonate layers. The chert layers can be subdivided into black layers (containing organic material and pyrite), red layers (containing hematite), and green layers (containing siderite). [5]
Banded iron formation from the Barberton Greenstone Belt, South Africa. A typical banded iron formation consists of repeated, thin layers (a few millimeters to a few centimeters in thickness) of silver to black iron oxides, either magnetite (Fe 3 O 4) or hematite (Fe 2 O 3), alternating with bands of iron-poor chert, often red in color, of similar thickness.
There are indications that the Iceman, also known as Ötzi, may have used iron pyrite to make fire. [5] From the Iron Age forward, until the invention of the friction match in the early 1800s by John Walker, the use of flint and steel was a common method of fire lighting.
Marcasite reacts more readily than pyrite under conditions of high humidity. The product of this disintegration is iron(II) sulfate and sulfuric acid. The hydrous iron sulfate forms a white powder consisting of the mineral melanterite, FeSO 4 ·7H 2 O. [13] This disintegration of marcasite in mineral collections is known as "pyrite decay".
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