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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Ball-and-stick model of a sulfamic acid zwitterion as it occurs in the crystal state. [4]The compound is well described by the formula H 3 NSO 3, not the tautomer H 2 NSO 2 (OH). The relevant bond distances are 1.44 Å for the S=O and 1.77 Å for the S–N.
The structure of hydrogen disulfide is similar to that of hydrogen peroxide, with C 2 point group symmetry. Both molecules are distinctly nonplanar. The dihedral angle between the H a −S−S and S−S−H b planes is 90.6°, compared with 111.5° in H 2 O 2. The H−S−S bond angle is 92°, close to 90° for unhybridized divalent sulfur. [1]
Sulfuric(IV) acid (United Kingdom spelling: sulphuric(IV) acid), also known as sulfurous (UK: sulphurous) acid and thionic acid, [citation needed] is the chemical compound with the formula H 2 SO 3. Raman spectra of solutions of sulfur dioxide in water show only signals due to the SO 2 molecule and the bisulfite ion, HSO − 3. [2]
The name octasulfur is the most commonly used for this chemical. It is systematically named cyclo-octasulfur (which is the preferred IUPAC name) and cyclooctasulfane.It is also the final member of the thiocane heterocylic series, where every carbon atom is substituted with a sulfur atom, thus this sulfur allotrope is systematically named octathiocane as well.
CH 3 CHO + NH 3 + H 2 → CH 3 CH 2 NH 2 + H 2 O. Ethylamine can be prepared by several other routes, but these are not economical. Ethylene and ammonia combine to give ethylamine in the presence of a sodium amide or related basic catalysts. [5] H 2 C=CH 2 + NH 3 → CH 3 CH 2 NH 2. Hydrogenation of acetonitrile, acetamide, and nitroethane ...
2 O 2− 5), also known as disulfite: 2 HSO − 3 ⇌ S 2 O 2− 5 + H 2 O. Because of this equilibrium, anhydrous sodium and potassium salts of bisulfite cannot be obtained. However, there are some reports of anhydrous bisulfites with large counter ions. [4] Structure of disulfite (aka metabisulfite) ion. [5]
The best Lewis structure for an oxocarbenium ion contains an oxygen–carbon double bond, with the oxygen atom attached to an additional group and consequently taking on a formal positive charge. In the language of canonical structures (or "resonance"), the polarization of the π bond is described by a secondary carbocationic resonance form ...