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Isopropenyl acetate is an organic compound, which is the acetate ester of the enol tautomer of acetone. This colorless liquid is significant commercially as the principal precursor to acetylacetone .
Isopropyl acetate decomposes slowly on contact with steel in the presence of air, producing acetic acid and isopropanol. It reacts violently with oxidizing materials and it attacks many plastics. [5] Isopropyl acetate is quite flammable in both its liquid and vapor forms, and it may be harmful if swallowed or inhaled. [6]
In a novel kilogram-scale metal-free Meerwein arylation the diazonium salt is formed from 2-nitroaniline, the alkene isopropenyl acetate is an adduct of propyne and acetic acid and the reaction product 2-nitrophenylacetone: [7] Metal free meerwein arylation
Isopropenyl acetate This page was last edited on 12 December 2022, at 05:27 (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 ...
The enzyme acetylacetone dioxygenase cleaves a central carbon-carbon bond of acetylacetone, producing acetate and 2-oxopropanal. The enzyme is iron(II)-dependent, but it has been proven to bind to zinc as well. Acetylacetone degradation has been characterized in the bacterium Acinetobacter johnsonii. [13] CH 3 C(O)CH 2 C(O)CH 3 + O 2 → CH 3 ...
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In organic chemistry, 1-propenyl (or simply propenyl) has the formula CH=CHCH 3 and 2-propenyl (isopropenyl) has the formula CH 2 =C-CH 3. These groups are found in many compounds. Propenyl compounds are isomeric with allyl compounds, which have the formula CH 2-CH=CH 2.
From left to right: the two isomeric groups propyl and 1-methylethyl (iPr or isopropyl), and the non-isomeric cyclopropyl group. In organic chemistry, a propyl group is a three-carbon alkyl substituent with chemical formula −CH 2 CH 2 CH 3 for the linear form.
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