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Zinc nitrate is usually prepared by dissolving zinc metal, zinc oxide, or related materials in nitric acid: Zn + 2 HNO 3 → Zn(NO 3) 2 + H 2 ZnO + 2 HNO 3 → Zn(NO 3) 2 + H 2 O. These reactions are accompanied by the hydration of the zinc nitrate. The anhydrous salt arises by the reaction of anhydrous zinc chloride with nitrogen dioxide: [1]
Zinc is a strong reducing agent with a standard redox potential of −0.76 V. Pure zinc tarnishes rapidly in air, rapidly forming a passive layer. The composition of this layer can be complex, but one constituent is probably basic zinc carbonate, Zn 5 (OH) 6 CO 3. [8] The reaction of zinc with water is slowed by this passive layer.
Zinc borate refers to a family of inorganic compounds consisting of borate of zinc. They are white solids with the formulas 4ZnO·B 2 O 3 ·H 2 O, ZnO·B 2 O 3 ·1.12H 2 O, ZnO·B 2 O 3 ·∼2H 2 O, 6ZnO·5B 2 O 3 ·3H 2 O, 2ZnO·3B 2 O 3 ·7H 2 O, 2ZnO·3B 2 O 3 ·3H 2 O, 3ZnO·5B 2 O 3 ·14H 2 O, and ZnO·5B 2 O 3 ·4.5H 2 O.
The reaction produces a primary, secondary, or tertiary alcohol via a 1,2-addition. The Barbier reaction is advantageous because it is a one-pot process: the organozinc reagent is generated in the presence of the carbonyl substrate. Organozinc reagents are also less water sensitive, thus this reaction can be conducted in water.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
It is a multi-step nitrogen fixation reaction that uses electrical arcs to react atmospheric nitrogen (N 2) with oxygen (O 2), ultimately producing nitric acid (HNO 3) with water. [1] The resultant nitric acid was then used as a source of nitrate (NO 3 − ) in the reaction HNO 3 + H 2 O H 3 O + + NO 3 − {\textstyle {\ce {HNO3 + H2O -> H3O ...
Zinc nitride reacts violently with water to form ammonia and zinc oxide. [3] [4] Zn 3 N 2 + 3 H 2 O → 3 ZnO + 2 NH 3. Zinc nitride reacts with lithium (produced in an electrochemical cell) by insertion. The initial reaction is the irreversible conversion into LiZn in a matrix of beta-Li 3 N. These products then can be converted reversibly and ...
They have the lowest melting points among all transition metals. [8] Zinc is bluish-white and lustrous, [9] though most common commercial grades of the metal have a dull finish. [10] Zinc is also referred to in nonscientific contexts as spelter. [11] Cadmium is soft, malleable, ductile, and with a bluish-white color. Mercury is a liquid, heavy ...