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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
In a dispersive medium, the phase speed itself depends upon the frequency of the wave, making the relationship between wavelength and frequency nonlinear. In the case of electromagnetic radiation—such as light—in free space, the phase speed is the speed of light, about 3 × 10 8 m/s.
As a wave, light is characterized by a velocity (the speed of light), wavelength, and frequency. As particles, light is a stream of photons . Each has an energy related to the frequency of the wave given by Planck's relation E = hf , where E is the energy of the photon, h is the Planck constant , 6.626 × 10 −34 J·s, and f is the frequency ...
For example, for visible light, the refractive index of glass is typically around 1.5, meaning that light in glass travels at c / 1.5 ≈ 200 000 km/s (124 000 mi/s); the refractive index of air for visible light is about 1.0003, so the speed of light in air is about 90 km/s (56 mi/s) slower than c.
is the speed of light (i.e. phase velocity) in a medium with permeability μ, and permittivity ε, and ∇ 2 is the Laplace operator. In a vacuum, v ph = c 0 = 299 792 458 m/s, a fundamental physical constant. [1] The electromagnetic wave equation derives from Maxwell's equations.
In chemistry and optical engineering ... probes of the photon mass than the frequency dependence of the speed of light. ... give the correct formula for the energy ...
For example, a wavenumber in inverse centimeters can be converted to a frequency expressed in the unit gigahertz by multiplying by 29.979 2458 cm/ns (the speed of light, in centimeters per nanosecond); [5] conversely, an electromagnetic wave at 29.9792458 GHz has a wavelength of 1 cm in free space.
since / = 1.239 841 984... × 10 −6 eV⋅m [4] where h is the Planck constant, c is the speed of light, and e is the elementary charge. The photon energy of near infrared radiation at 1 μm wavelength is approximately 1.2398 eV.