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Supercritical ethane, fluid. [1] In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas ...
Water activity is the thermodynamic activity of water as solvent and the relative humidity of the surrounding air after equilibration. As temperature increases, a w typically increases, except in some products with crystalline salt or sugar. Water migrates from areas of high a w to areas of low a w. For example, if honey (a w ≈ 0.6) is ...
Description. The central result of classical nucleation theory is a prediction for the rate of nucleation , in units of (number of events)/ (volume·time). For instance, a rate in a supersaturated vapor would correspond to an average of 1000 droplets nucleating in a volume of 1 cubic meter in 1 second. The CNT prediction for is [3] where.
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
The Flory–Fox equation relates the number-average molecular weight, M n, to the glass transition temperature, T g, as shown below: =, where T g,∞ is the maximum glass transition temperature that can be achieved at a theoretical infinite molecular weight and K is an empirical parameter that is related to the free volume present in the polymer sample.
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The Streeter–Phelps equation is also known as the DO sag equation. This is due to the shape of the graph of the DO over time. The biological oxygen demand (BOD) and dissolved oxygen (DO) curves in a river flowing right reaching equilibrium after a continuous input of high BOD influent is added into the river at x = 15 m and t = 0 s.
In colloidal and surface chemistry, the critical micelle concentration (CMC) is defined as the concentration of surfactants above which micelles form and all additional surfactants added to the system will form micelles. [1] The CMC is an important characteristic of a surfactant. Before reaching the CMC, the surface tension changes strongly ...