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There are a number of effects which control spectral line shape. A spectral line extends over a tiny spectral band with a nonzero range of frequencies, not a single frequency (i.e., a nonzero spectral width). In addition, its center may be shifted from its nominal central wavelength. There are several reasons for this broadening and shift.
The Fraunhofer lines are typical spectral absorption lines. Absorption lines are narrow regions of decreased intensity in a spectrum, which are the result of photons being absorbed as light passes from the source to the detector. In the Sun, Fraunhofer lines are a result of gas in the Sun's atmosphere and outer photosphere. These regions have ...
The Siegbahn notation is used in X-ray spectroscopy to name the spectral lines that are characteristic to elements. It was introduced by Manne Siegbahn.. The characteristic lines in X-ray emission spectra correspond to atomic electronic transitions where an electron jumps down to a vacancy in one of the inner shells of an atom.
The spectrum appears in a series of lines called the line spectrum. This line spectrum is called an atomic spectrum when it originates from an atom in elemental form. Each element has a different atomic spectrum. The production of line spectra by the atoms of an element indicate that an atom can radiate only a certain amount of energy.
Spectroscopists customarily refer to the spectrum arising from a given ionization state of a given element by the element's symbol followed by a Roman numeral.The numeral I is used for spectral lines associated with the neutral element, II for those from the first ionization state, III for those from the second ionization state, and so on. [1]
If the same pattern of intervals is seen in an observed spectrum from a distant source but occurring at shifted wavelengths, it can be identified as hydrogen too. If the same spectral line is identified in both spectra—but at different wavelengths—then the redshift can be calculated using the table below.
In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian , Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. [ 1 ]