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Dinickel boride is a chemical compound of nickel and boron with formula Ni 2 B. [1] [2] It is one of the borides of nickel.The formula "Ni2 B" and the name "nickel boride" are often used for a nickel-boron catalyst obtained by reacting nickel salts with sodium borohydride.
Aromatic C–H borylation was developed by John F. Hartwig and Ishiyama using the diboron reagent Bis(pinacolato)diboron catalyzed by 4,4’-di-tert-butylbipyridine (dtbpy) and [Ir(COD)(OMe)] 2. [15] With this catalyst system the borylation of aromatic C–H bonds occurs with regioselectivity that is controlled by steric effects of the starting ...
Boron-boron multiple bonds are rare, but can be stabilized by NHC adducts. One example is the diborene (RHB=BHR): [20] [21] Each boron atom has an attached proton and is coordinated to a NHC carbene. The parent structure with the additional carbene ligands is diborane(2). [22] [23] A reported diboryne is based on similar chemistry. [24]
Thexylborane [Me 2 CHCMe 2 BH 2] 2 (Me = methyl) is a rare, easily accessed monoalkylborane. One example of a monoalkylborane is thexylborane (ThxBH 2), produced by the hydroboration of tetramethylethylene: [14] B 2 H 6 + 2 Me 2 C=CMe 2 → [Me 2 CHCMe 2 BH 2] 2. A chiral example is monoisopinocampheylborane. Although often written as IpcBH 2 ...
The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH 3) 2 Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boron–boron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B 2 (OCH 3) 4, to produce what they termed sub-boric acid. [4]
Nickel boride is the common name of materials composed chiefly of the elements nickel and boron that are widely used as catalysts in organic chemistry. [1] [2] Their approximate chemical composition is Ni 2.5 B, [3] and they are often incorrectly denoted "Ni 2 B" in organic chemistry publications.
The boron reagent is converted to boric acid. The reaction was originally described by H.C. Brown in 1957 for the conversion of 1-hexene into 1-hexanol. [3] Hexanol synthesis. Knowing that the group containing the boron will be replaced by a hydroxyl group, it can be seen that the initial hydroboration step determines the regioselectivity.
Alpine borane is the commercial name for an organoboron compound that is used in organic synthesis. It is a colorless liquid, although it is usually encountered as a solution. A range of alkyl-substituted borane are specialty reagents in organic synthesis. Two such reagents that are closely related to Alpine borane are 9-BBN and ...