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The distinction is relevant when product A forms faster than product B because the activation energy for product A is lower than that for product B, yet product B is more stable. In such a case A is the kinetic product and is favoured under kinetic control and B is the thermodynamic product and is favoured under thermodynamic control. [1] [2] [3]
This type of chemical thermodynamic equilibrium will persist indefinitely unless the system is changed. Chemical systems might undergo changes in the phase of matter or a set of chemical reactions. State A is said to be more thermodynamically stable than state B if the Gibbs free energy of the change from A to B is positive.
A reaction coordinate diagram can also be used to qualitatively illustrate kinetic and thermodynamic control in a reaction. Figure 9:Kinetic and Thermodynamic Control: A. Product B is both the kinetic and thermodynamic product and B. Product A is the kinetic product while B is the thermodynamic product. [4]
Being "stuck" in a thermodynamic trough without being at the lowest energy state is known as having kinetic stability or being kinetically persistent. The particular motion or kinetics of the atoms involved has resulted in getting stuck, despite there being preferable (lower-energy) alternatives.
[5] In fact, if the ground-state energy behaves proportional to for some , then pouring two glasses of water would provide an energy proportional to () = (), which is enormous for large . A system is called stable of the second kind or thermodynamically stable when the free energy is bounded from below by a linear function of N {\displaystyle N} .
If a system has a definite temperature, then its total energy has three distinguishable components, termed kinetic energy (energy due to the motion of the system as a whole), potential energy (energy resulting from an externally imposed force field), and internal energy. The establishment of the concept of internal energy distinguishes the ...
Food is similar to hydrocarbon and carbohydrate fuels, and when it is oxidized, its energy release is similar (though assessed differently than for a hydrocarbon fuel — see food energy). In chemical thermodynamics, the term used for the chemical potential energy is chemical potential, and sometimes the Gibbs-Duhem equation is used.
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
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