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The length of the carbonhydrogen bond varies slightly with the hybridisation of the carbon atom. A bond between a hydrogen atom and an sp 2 hybridised carbon atom is about 0.6% shorter than between hydrogen and sp 3 hybridised carbon. A bond between hydrogen and sp hybridised carbon is shorter still, about 3% shorter than sp 3 C-H.
In nylon, hydrogen bonds between carbonyl and the amide NH effectively link adjacent chains, which gives the material mechanical strength. Hydrogen bonds also affect the aramid fibre, where hydrogen bonds stabilize the linear chains laterally. The chain axes are aligned along the fibre axis, making the fibres extremely stiff and strong.
The main engineering strategies currently in use are hydrogen-and halogen bonding and coordination bonding. [2] These may be understood with key concepts such as the supramolecular synthon and the secondary building unit. [3] An example of crystal engineering using hydrogen bonding reported by Wuest and coworkers in J. Am. Chem. Soc., 2007 ...
In organic chemistry and organometallic chemistry, carbon–hydrogen bond activation (C−H activation) is a type of organic reaction in which a carbon–hydrogen bond is cleaved and replaced with a C−X bond (X ≠ H is typically a main group element, like carbon, oxygen, or nitrogen).
Molecular binding is an attractive interaction between two molecules that results in a stable association in which the molecules are in close proximity to each other. It is formed when atoms or molecules bind together by sharing of electrons.
The σ from the 2p is more non-bonding due to mixing, and same with the 2s σ. This also causes a large jump in energy in the 2p σ* orbital. The bond order of diatomic nitrogen is three, and it is a diamagnetic molecule. [12] The bond order for dinitrogen (1σ g 2 1σ u 2 2σ g 2 2σ u 2 1π u 4 3σ g 2) is three because two electrons are now ...
Crash Course (sometimes stylized as CrashCourse) is an educational YouTube channel started by John Green and Hank Green (collectively the Green brothers), who became known on YouTube through their Vlogbrothers channel. [2] [3] [4] Crash Course was one of the hundred initial channels funded by YouTube's $100 million original channel initiative.
In ethene, the two carbon atoms form a σ bond by overlapping one sp 2 orbital from each carbon atom. The π bond between the carbon atoms perpendicular to the molecular plane is formed by 2p–2p overlap. Each carbon atom forms covalent C–H bonds with two hydrogens by s–sp 2 overlap, all with 120° bond angles. The hydrogen–carbon bonds ...