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Two commercially important halide minerals are halite and fluorite. The former is a major source of sodium chloride, in parallel with sodium chloride extracted from sea water or brine wells. Fluorite is a major source of hydrogen fluoride , complementing the supply obtained as a byproduct of the production of fertilizer.
Halite is also often used both residentially and municipally for managing ice. Because brine (a solution of water and salt) has a lower freezing point than pure water, putting salt or saltwater on ice that is below 0 °C (32 °F) will cause it to melt—this effect is called freezing-point depression .
Above this temperature, liquid water saturated with salt can exist in equilibrium with hydrohalite. Hydrohalite has a strong positive temperature coefficient of solubility, unlike halite. [2] Hydrohalite decomposes at 0.1°C, giving a salty brine and solid halite. Under pressure, hydrohalite is stable between 7,900 and 11,600 atmospheres pressure.
Trapped in a time capsule the same size as the diameter of a human hair, the ore-forming liquid in this inclusion was so hot and contained so much dissolved solids that when it cooled, crystals of halite, sylvite, gypsum, and hematite formed. As the samples cooled, the fluid shrank more than the surrounding mineral, and created a vapor bubble.
It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical ...
It is used as a fertilizer. Polyhalite was first described in 1818 for specimens from its type locality in Salzburg, Austria. [2] It occurs in sedimentary marine evaporites and is a major potassium ore mineral in the Carlsbad deposits of New Mexico. It is also present as a 2–3% contaminant of Himalayan salt.
Carnallite is an uncommon double chloride mineral that only forms under specific environmental conditions in an evaporating sea or sedimentary basin. It is mined for both potassium and magnesium and occurs in the evaporite deposits of Carlsbad, New Mexico ; the Paradox Basin in Colorado and Utah ; Stassfurt , Germany ; the Perm Basin , Russia ...
Zabuyelite is the natural mineral form of lithium carbonate, with a formula Li 2 C O 3. It was discovered in 1987 at Lake Zabuye, Tibet, after which it is named. It forms colorless vitreous monoclinic crystals. It occurs as inclusions within halite in lithium rich evaporites and as solid phase in fluid inclusions in the mineral spodumene.
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