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Delta-sigma (ΔΣ; or sigma-delta, ΣΔ) modulation is an oversampling method for encoding signals into low bit depth digital signals at a very high sample-frequency as part of the process of delta-sigma analog-to-digital converters (ADCs) and digital-to-analog converters (DACs).
To achieve high signal-to-noise ratio, delta modulation must use oversampling techniques, that is, the analog signal is sampled at a rate several times higher than the Nyquist rate. Derived forms of delta modulation are continuously variable slope delta modulation, delta-sigma modulation, and differential modulation.
In chemistry, sigma bonds (σ bonds) or sigma overlap are the strongest type of covalent chemical bond. [1] They are formed by head-on overlapping between atomic orbitals along the internuclear axis. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is ...
It is a special case of a C–H sigma complex. Historically, agostic complexes were the first examples of C–H sigma complexes to be observed spectroscopically and crystallographically, due to intramolecular interactions being particularly favorable and more often leading to robust complexes.
Hyperconjugation can be used to rationalize a variety of chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals, and the thermodynamic Zaitsev's rule for alkene stability.
The complete function of delta modulation, VAC, and echo control for 6 ports was implemented in a single digital integrated circuit chip with 12-bit arithmetic. A single DAC was shared by all 6 ports providing voltage compare functions for the modulators and feeding sample and hold circuits for the demodulator outputs.
In Organic chemistry, the inductive effect in a molecule is a local change in the electron density due to electron-withdrawing or electron-donating groups elsewhere in the molecule, resulting in a permanent dipole in a bond. [1] It is present in a σ (sigma) bond, unlike the electromeric effect which is present in a π (pi) bond.
The triplet and singlet excitation energies of a sigma bond can be used to determine if a bond will follow the homolytic or heterolytic pathway. [2] A metal−metal sigma bond is an exception because the bond's excitation energy is extremely high, thus cannot be used for observation purposes. [2] In some cases, bond cleavage requires catalysts.