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Sphalerite, the more common polymorph of zinc sulfide Wurtzite, the less common polymorph of zinc sulfide. ZnS exists in two main crystalline forms. This dualism is an example of polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite.
The refractive index of sphalerite (as measured via sodium light, average wavelength 589.3 nm) ranges from 2.37 when it is pure ZnS to 2.50 when there is 40% iron content. [6] Sphalerite is isotropic under cross-polarized light, however sphalerite can experience birefringence if intergrown with its polymorph wurtzite; the birefringence can ...
This is also known as the sphalerite structure or the Structurbericht designation B3. Pages in category "Zincblende crystal structure" The following 36 pages are in this category, out of 36 total.
Wurtzite is a zinc and iron sulfide mineral with the chemical formula (Zn,Fe)S, a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent. [5] It is trimorphous with matraite and sphalerite. [2] It occurs in hydrothermal deposits associated with sphalerite, pyrite, chalcopyrite ...
Crystallographically the structure of chalcopyrite is closely related to that of zinc blende ZnS . [18] The unit cell is twice as large, reflecting an alternation of Cu + and Fe 3+ ions replacing Zn 2+ ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S 2− sulfide anions
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Zinc sulfide, ZnS, crystallizes in two closely related structures, the zincblende crystal structure and the Wurtzite crystal structure, which are common structures of compounds with the formula MA. Both Zn and S are tetrahedrally coordinated by the other ion. A useful property of ZnS is its phosphorescence.
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