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Lithium chloride is a chemical compound with the formula Li Cl.The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li + ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
Solubility of LiCl in various solvents (g LiCl / 100g of solvent at 25 °C) H 2 O: 84.5 Liquid ammonia: 3.02 Liquid sulfur dioxide: 0.012 Methanol: 21 - 41 Formic acid: 27.5 Sulfolane: 1.5 Acetonitrile: 0.14 Acetone: 0.83 Formamide: 28.2 Dimethylformamide: 11 - 28 Reference: Burgess, J. Metal Ions in Solution (Ellis Horwood, New York, 1978 ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The hydrated lithium cation in water is probably tetrahedral and four-coordinated. [27] There are most probably six water molecules in the primary solvation sphere of the octahedral sodium ion. [27] [28] Potassium is seven-coordinate, and rubidium and caesium are probably eight-coordinate square antiprismatic. [27] No data is available for ...
Its solubility in water is low relative to other lithium salts. The isolation of lithium from aqueous extracts of lithium ores capitalizes on this poor solubility. Its apparent solubility increases 10-fold under a mild pressure of carbon dioxide; this effect is due to the formation of the metastable lithium bicarbonate, which is more soluble ...
It does not occur freely in nature, but occurs mainly as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride.
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water. It is mainly used as a component of molten salts. [4]