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In the lab, phenyl-2-nitropropene is produced by the reaction of benzaldehyde and nitroethane in the presence of a basic catalyst like n-butylamine.The reaction is a nitroaldol reaction, and is a variant of a Knoevenagel condensation reaction, which is one of a broader class of reactions called Henry condensations, or simply Henry reactions.
Phenylpropenes broadly are compounds containing a phenyl ring bonded to propene, more specifically those with an allyl group bonded to a benzene ring, having the parent structure of allylbenzene. These comprise a class of phenylpropanoids , where there are typically other substituents bonded to the aromatic ring.
2-bromo-1-phenylpentan-1-one substituted cathinones and substituted amphetamines: 2-bromo-1-phenylpropan-1-one substituted cathinones and substituted amphetamines: BMK glycidic acid and esters methamphetamine 3-oxo-2-phenylbutanoic acid and its esters methamphetamine 3,4-methylenedioxyphenyl-2-nitropropene (MDP2NP) MDMA: Ammonia gas
Via condensations like the Henry reaction, nitroethane converts to several compounds of commercial interest.Condensation with 3,4-dimethoxybenzaldehyde affords the precursor to the antihypertensive drug methyldopa; condensation with unsubstituted benzaldehyde yields phenyl-2-nitropropene, a precursor for amphetamine drugs.
In the so-called Ter Meer reaction (1876) named after Edmund ter Meer, [14] the reactant is a 1,1-halonitroalkane: The reaction mechanism is proposed in which in the first slow step a proton is abstracted from nitroalkane 1 to a carbanion 2 followed by protonation to an aci-nitro 3 and finally nucleophilic displacement of chlorine based on an ...
Amygdalin 2 H 2 O HCN benzaldehyde 2 × glucose 2 × Benzaldehyde contributes to the scent of oyster mushrooms (Pleurotus ostreatus). Reactions Benzaldehyde is easily oxidized to benzoic acid in air at room temperature, causing a common impurity in laboratory samples. Since the boiling point of benzoic acid is much higher than that of benzaldehyde, it may be purified by distillation. Benzyl ...
Phenylacetone, also known as phenyl-2-propanone, is an organic compound with the chemical formula C 6 H 5 CH 2 COCH 3. It is a colorless oil that is soluble in organic solvents. It is a mono-substituted benzene derivative, consisting of an acetone attached to a phenyl group. As such, its systematic IUPAC name is 1-phenyl-2-propanone.
This category includes chemical compounds that include a phenyl group, C 6 H 5 –. (That is, benzene with only one substituent or bond.) For benzene derivatives ( derivatives or structural analogs of benzene ) in which benzene has multiple substituents or bonds, see the parent category, Category:Benzene derivatives .