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Carbene intramolecular reaction Carbene intermolecular reaction. The 1,2-rearrangement produced from intramolecular insertion into a bond adjacent to the carbene center is a nuisance in some reaction schemes, as it consumes the carbene to yield the same effect as a traditional elimination reaction. [16]
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Carbyne molecules are generally found to be in electronic doublet states: the non-bonding electrons on carbon are arranged as one radical (unpaired electron) and one electron pair, leaving a vacant atomic orbital, rather than being a triradical (the quartet state).
The Wheel of Fortune from Carmina Burana. Carmina Burana (/ ˈ k ɑːr m ɪ n ə b ʊ ˈ r ɑː n ə /, Latin for "Songs from Benediktbeuern" [Buria in Latin]) is a manuscript of 254 [1] poems and dramatic texts mostly from the 11th or 12th century, although some are from the 13th century.
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Music examples are an obviously valuable and necessary addition to Wikipedia, often superior to text. These are both far more valuable and far more free than music samples being abstract categories applicable to multiple examples without any of the copyright or other law applicable to samples.
The carbene compound may include a bioorthogonal tag or handle by which the protein of interest can be isolated. The protein can then be digested and sequenced by mass spectrometry in order to identify which residues the carbene containing ligand is bound to, and hence the identity of the binding site in the receptor.