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  2. Brønsted–Lowry acid–base theory - Wikipedia

    en.wikipedia.org/wiki/Brønsted–Lowry_acid...

    This is best illustrated by an equilibrium equation. acid + base ⇌ conjugate base + conjugate acid. With an acid, HA, the equation can be written symbolically as: + + + The equilibrium sign, ⇌, is used because the reaction can occur in both forward and backward directions (is reversible).

  3. Brønsted catalysis equation - Wikipedia

    en.wikipedia.org/wiki/Brønsted_catalysis_equation

    A plot of the common logarithm of the reaction rate constant k versus the logarithm of the ionization constant K a for a series of acids (for example a group of substituted phenols or carboxylic acids) gives a straight line with slope α and intercept C. The Brønsted equation is a free-energy relationship.

  4. Conjugate (acid-base theory) - Wikipedia

    en.wikipedia.org/wiki/Conjugate_(acid-base_theory)

    An example of this case would be the splitting of hydrochloric acid HCl in water. Since HCl is a strong acid (it splits up to a large extent), its conjugate base (Cl −) will be weak. Therefore, in this system, most H + will be hydronium ions H 3 O + instead of attached to Cl − anions and the conjugate bases will be weaker than water molecules.

  5. Johannes Nicolaus Brønsted - Wikipedia

    en.wikipedia.org/wiki/Johannes_Nicolaus_Brønsted

    Later in his career, Brønsted kept studying reaction kinetics, with a special focus on reactions taking place in non-aqueous solutions. He also developed some work about the effect of molecular size on the thermodynamical properties of hydrocarbons, polymers and colloids. [ 7 ]

  6. Lewis acids and bases - Wikipedia

    en.wikipedia.org/wiki/Lewis_acids_and_bases

    The equation is −ΔH = E A E B + C A C B + W. The W term represents a constant energy contribution for acid–base reaction such as the cleavage of a dimeric acid or base. The equation predicts reversal of acids and base strengths. The graphical presentations of the equation show that there is no single order of Lewis base strengths or Lewis ...

  7. Deep eutectic solvent - Wikipedia

    en.wikipedia.org/wiki/Deep_eutectic_solvent

    Deep eutectic solvents or DESs are solutions of Lewis or Brønsted acids and bases which form a eutectic mixture. [1] Deep eutectic solvents are highly tunable through varying the structure or relative ratio of parent components and thus have a wide variety of potential applications including catalytic, separation, and electrochemical processes.

  8. Singular solution - Wikipedia

    en.wikipedia.org/wiki/Singular_solution

    A singular solution y s (x) of an ordinary differential equation is a solution that is singular or one for which the initial value problem (also called the Cauchy problem by some authors) fails to have a unique solution at some point on the solution. The set on which a solution is singular may be as small as a single point or as large as the ...

  9. Bjerrum plot - Wikipedia

    en.wikipedia.org/wiki/Bjerrum_plot

    Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...

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