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Any non-linear differentiable function, (,), of two variables, and , can be expanded as + +. If we take the variance on both sides and use the formula [11] for the variance of a linear combination of variables (+) = + + (,), then we obtain | | + | | +, where is the standard deviation of the function , is the standard deviation of , is the standard deviation of and = is the ...
The errors inherent in either BSSE correction disappear more rapidly than the total value of BSSE in larger basis sets. [11] See also. Basis set (chemistry) Quantum ...
Systematic errors are errors that are not determined by chance but are introduced by repeatable processes inherent to the system. [5] Sources of systematic errors include errors in equipment calibration, uncertainty in correction terms applied during experimental analysis, errors due the use of approximate theoretical models.
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
It is remarkable that the sum of squares of the residuals and the sample mean can be shown to be independent of each other, using, e.g. Basu's theorem.That fact, and the normal and chi-squared distributions given above form the basis of calculations involving the t-statistic:
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For a confidence level, there is a corresponding confidence interval about the mean , that is, the interval [, +] within which values of should fall with probability . ...
Statements about relative errors are sensitive to addition of constants, but not to multiplication by constants. For absolute errors, the opposite is true: ...